O-XYLENE | CAMEO Chemicals | NOAA (2024)

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Chemical Datasheet

O-XYLENE | CAMEO Chemicals | NOAA (1)

ChemicalIdentifiers | Hazards | ResponseRecommendations |PhysicalProperties |RegulatoryInformation | AlternateChemicalNames

Chemical Identifiers

What is this information?

The Chemical Identifier fields include common identification numbers, theNFPA diamond U.S. Department of Transportation hazard labels, and a general description of the chemical. The information in CAMEO Chemicals comes from a variety of data sources.

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 95-47-6 O-XYLENE | CAMEO Chemicals | NOAA (2)
  • 1307
  • Flammable Liquid
  • O-XYLENE | CAMEO Chemicals | NOAA (3) XLO
NIOSH Pocket Guide International Chem Safety Card
o-XyleneO-XYLENE | CAMEO Chemicals | NOAA (4)

NFPA 704

Diamond Hazard Value Description
3
20
O-XYLENE | CAMEO Chemicals | NOAA (6) Health 2 Can cause temporary incapacitation or residual injury.
O-XYLENE | CAMEO Chemicals | NOAA (7) Flammability 3 Can be ignited under almost all ambient temperature conditions.
O-XYLENE | CAMEO Chemicals | NOAA (8) Instability 0 Normally stable, even under fire conditions.
O-XYLENE | CAMEO Chemicals | NOAA (9) Special

(NFPA, 2010)

General Description

A colorless watery liquid with a sweet odor. Less dense than water. Insoluble in water. Irritating vapor. (USCG, 1999)

Hazards

What is this information?

The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. The information in CAMEO Chemicals comes from a variety of data sources.

Reactivity Alerts

  • Highly Flammable

Air & Water Reactions

Highly flammable. Insoluble in water.

Fire Hazard

Behavior in Fire: Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back. (USCG, 1999)

Health Hazard

Vapors cause headache and dizziness. Liquid irritates eyes and skin. If taken into lungs, causes severe coughing, distress, and rapidly developing pulmonary edema. If ingested, causes nausea, vomiting, cramps, headache, and coma. Can be fatal. Kidney and liver damage can occur. (USCG, 1999)

Reactivity Profile

O-XYLENE may react with oxidizing materials. (NTP, 1992).

Belongs to the Following Reactive Group(s)

  • Hydrocarbons, Aromatic

Potentially Incompatible Absorbents

No information available.

Response Recommendations

What is this information?

The Response Recommendation fields include isolation and evacuation distances, as well as recommendations for firefighting, non-fire response, protective clothing, and first aid. The information in CAMEO Chemicals comes from a variety of data sources.

Isolation and Evacuation

Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.

LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).

FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)

Firefighting

Fire Extinguishing Agents Not to Be Used: Water may be ineffective.

Fire Extinguishing Agents: Foam, dry chemical, or carbon dioxide (USCG, 1999)

Non-Fire Response

SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

STORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)

Protective Clothing

Excerpt from NIOSH Pocket Guide for o-XyleneO-XYLENE | CAMEO Chemicals | NOAA (10):

Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.

Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.

Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.

Remove: WHEN WET (FLAMMABLE) - Work clothing that becomes wet should be immediately removed due to its flammability hazard (i.e., for liquids with a flash point <100°F).

Change: No recommendation is made specifying the need for the worker to change clothing after the workshift. (NIOSH, 2024)

DuPont Tychem® Suit Fabrics

Fabric legend, testing details, and a caution from DuPont

Tychem® Fabric Legend

QS = Tychem 2000 SFR
QC = Tychem 2000
SL = Tychem 4000
C3 = Tychem 5000
TF = Tychem 6000
TP = Tychem 6000 FR
RC = Tychem RESPONDER® CSM
TK = Tychem 10000
RF = Tychem 10000 FR

Testing Details

The fabric permeation data was generated for DuPont by a third party laboratory. Permeation data for industrial chemicals is obtained per ASTM F739. Normalized breakthrough times (the time at which the permeation rate exceeds 0.1 μg/cm2/min) are reported in minutes. All chemicals have been tested between approximately 20°C and 27°C unless otherwise stated. All chemicals have been tested at a concentration of greater than 95% unless otherwise stated.

Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% relative humidity per military standard MIL-STD-282. "Breakthrough time" for chemical warfare agents is defined as the time when the cumulative mass which permeated through the fabric exceeds the limit in MIL-STD-282 [either 1.25 or 4.0 μg/cm2].

A Caution from DuPont

This information is based upon technical data that DuPont believes to be reliable on the date issued. It is subject to revision as additional knowledge and experience are gained. The information reflects laboratory performance of fabrics, not complete garments, under controlled conditions. It is intended for informational use by persons having technical skill for evaluation under their specific end-use conditions, at their own discretion and risk. It is the user's responsibility to determine the level of toxicity and the proper personal protective equipment needed. Anyone intending to use this information should first verify that the garment selected is suitable for the intended use. In many cases, seams and closures have shorter breakthrough times and higher permeation rates than the fabric. If fabric becomes torn,abraded or punctured, or if seams or closures fail, or if attached gloves, visors, etc. are damaged, end user should discontinue use of garment to avoid potential exposure to chemical. Since conditions of use are outside our control, DuPont makes no warranties, express or implied, including, without limitation, no warranties of merchantability or fitness for a particular use and assume no liability in connection with any use of this information. This information is not intended as a license to operate under or a recommendation to infringe any patent, trademark or technical information of DuPont or others covering any material or its use.

Normalized Breakthrough Times (in Minutes)
Chemical CAS Number State QS QC SL C3 TF TP RC TK RF
Xylene, o- 95-47-6 Liquid >480

> indicates greater than.

Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. Only...

More Info...

...Tychem® ThermoPro, Tychem® Reflector® and Tychem® TK styles 600T/601T (with aluminized outer suit) garments are designed and tested to help reduce burn injury during escape from a flash fire. Users of Tychem® ThermoPro, Tychem® Reflector® and Tychem® TK styles 600T/601T (with aluminized outer suit) garments should not knowingly enter an explosive environment. Tychem® garments with attached socks must be worn inside protective outer footwear and are not suitable as outer footwear. These attached socks do not have adequate durability or slip resistance to be worn as the outer foot covering.

(DuPont, 2024)

First Aid

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Physical Properties

What is this information?

The Physical Property fields include properties such as vapor pressure and boiling point, as well as explosive limits and toxic exposure thresholds The information in CAMEO Chemicals comes from a variety of data sources.

Note: For Vapor Density and Specific Gravity, comparing the value to 1.0 can tell you if the chemical will likely sink/rise in air or sink/float in fresh water (respectively). Short phrases have been added to those values below as an aid. However, make sure to also consider the circ*mstances of a release. The Vapor Density comparisons are only valid when the gas escaping is at the same temperature as the surrounding air itself. If the chemical is escaping from a container where it was pressurized or refrigerated, it may first escape and behave as a heavy gas and sink in the air (even if it has a Vapor Density value less than 1). Also, the Specific Gravity comparisons are for fresh water (density 1.0 g/mL). If your spill is in salt water (density about 1.027 g/mL), you need to adjust the point of comparison. There are some chemicals that will sink in fresh water and float in salt water.

Chemical Formula:
  • C8H10

Flash Point: 63°F(NTP, 1992)

Lower Explosive Limit (LEL): 0.9 %(USCG, 1999)

Upper Explosive Limit (UEL): 6.7 %(USCG, 1999)

Autoignition Temperature: 869°F(USCG, 1999)

Melting Point: -13 to -9°F(NTP, 1992)

Vapor Pressure: 10 mmHgat 89.8°F(NTP, 1992)

Vapor Density (Relative to Air): 3.66 (NTP, 1992)- Heavier than air; will sink

Specific Gravity: 0.88 at 68°F(USCG, 1999)- Less dense than water; will float

Boiling Point: 289 to 293°Fat 760 mmHg(NTP, 1992)

Molecular Weight: 106.17 (NTP, 1992)

Water Solubility: Insoluble(NTP, 1992)

Ionization Energy/Potential:8.56 eV(NIOSH, 2024)

IDLH: 900 ppm(NIOSH, 2024)

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Xylene, m- (includes o- (95-47-6) and p- (106-42-3) isomers) 130 ppm 920 ppm 2500 ppm O-XYLENE | CAMEO Chemicals | NOAA (11) LEL = 11000 ppm

O-XYLENE | CAMEO Chemicals | NOAA (12) indicates value is 10-49% of LEL.

(DOE, 2024)

Regulatory Information

What is this information?

The Regulatory Information fields include information from the U.S. Environmental Protection Agency's Title III Consolidated List of Lists, the U.S. Cybersecurity and Infrastructure Security Agency's Chemical Facility Anti-Terrorism Standards, and the U.S. Occupational Safety and Health Administration's Process Safety Management of Highly Hazardous Chemicals Standard List (see more about these data sources).

EPA Consolidated List of Lists

Regulatory Name CAS Number/
313 Category Code
EPCRA 302
EHS TPQ
EPCRA 304
EHS RQ
CERCLA RQ EPCRA 313
TRI
RCRA
Code
CAA 112(r)
RMP TQ
Benzene, o-dimethyl- 95-47-6 1000 pounds X U239
o-Xylene 95-47-6 1000 pounds 313 U239
  • "X" indicates that this is a second name for an EPCRA section 313 chemical already included on this consolidated list. May also indicate that the same chemical with the same CAS number appears on another list with a different chemical name.

(EPA List of Lists, 2024)

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names

What is this information?

This section provides a listing of alternate names for this chemical, including trade names and synonyms.

  • BENZENE, O-DIMETHYL-
  • 1,2-DIMETHYLBENZENE
  • 2-METHYLTOLUENE
  • O-DIMETHYLBENZENE
  • O-METHYLTOLUENE
  • O-XYLENE
  • O-XYLOL
  • ORTHO-XYLENE
  • ORTHOXYLENE
  • 1,2-XYLENE
  • XYLENES (ORTHO-XYLENE)
  • XYLOL

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O-XYLENE | CAMEO Chemicals | NOAA (13)

Web site owner: Office of Response and RestorationO-XYLENE | CAMEO Chemicals | NOAA (14), National Ocean ServiceO-XYLENE | CAMEO Chemicals | NOAA (15), National Oceanic and Atmospheric AdministrationO-XYLENE | CAMEO Chemicals | NOAA (16). USA.govO-XYLENE | CAMEO Chemicals | NOAA (17).

CAMEO Chemicals version 3.1.0.

O-XYLENE | CAMEO Chemicals | NOAA (2024)

FAQs

Is xylene a hazardous waste? ›

► Keep Xylenes out of confined spaces, such as sewers, because of the possibility of an explosion. HAZARDOUS WASTE. Contact your state Department of Environmental Protection (DEP) or your regional office of the federal Environmental Protection Agency (EPA) for specific recommendations.

Is O-xylene flammable? ›

Highly flammable. Insoluble in water. O-XYLENE may react with oxidizing materials.

What are the precautions for xylene? ›

What Personal Protective Equipment (PPE) is needed when working with xylene? Eye/Face Protection: Wear chemical safety goggles. A face shield (with safety goggles) may also be necessary. Skin Protection: Wear chemical protective clothing e.g. gloves, aprons, boots.

Is xylene corrosive? ›

Xylene is a colorless, non-corrosive, flammable liquid with an aromatic odor similar to that of benzene (Henderson, 2001).

Why is xylene banned? ›

Acute (short- term) inhalation exposure to mixed xylenes in humans results in irritation of the eyes, nose, and throat, gastrointestinal effects, eye irritation, and neurological effects.

Is xylene harmful to humans? ›

Exposure to xylene can irritate the eyes, nose, skin, and throat. Xylene can also cause headaches, dizziness, confusion, loss of muscle coordination, and in high doses, death. Workers may be harmed from exposure to xylene. The level of exposure depends upon the dose, duration, and work being done.

What is the difference between xylene and O-xylene? ›

It is a constitutional isomer of m-xylene and p-xylene, the mixture being called xylene or xylenes. o-Xylene is a colourless slightly oily flammable liquid. Xylene is a colorless liquid that had a sweet odor. Xylene is flammable and practically insoluble.

How do you dispose of xylene? ›

Incineration: Xylene can be incinerated at high temperatures, which destroys the hazardous compounds. Landfilling: Xylene can be landfilled in a secure landfill that is designed to prevent the waste from leaching into the environment. Recycling: Xylene can be recycled into new products, such as plastics and solvents.

Why is o xylene used? ›

These compounds are aromatic hydrocarbons that are principally used as solvents, thinners, and as intermediates or feedstocks for the synthesis of other important commercial chemicals (e.g., plasticizers, perfumes, pharmaceuticals). Xylene is also a component of gasoline.

What happens when you mix xylene and water? ›

Xylene does not mix well with water; however, it does mix with alcohol and many other chemicals. Most people begin to smell xylene in air at 0.08–3.7 parts of xylene per million parts of air (ppm) and in water at 0.53–1.1 ppm.

How carcinogenic is xylene? ›

Both the International Agency for Research on Cancer (IARC) and the EPA have found that there is insufficient information to determine whether or not xylene is carcinogenic.

How long does xylene take to evaporate? ›

Xylene evaporates quickly, meaning that most xylene that gets into soil or water is released into the air and broken down by sunlight and less harmful chemicals within a couple of days. However, if xylene make its way down into underground water, it may remain for several months before being broken down.

What is the problem with xylene? ›

Breathing Xylenes for a short time affects the central nervous system, causing dizziness, sleepiness, irritability or confusion. Other symptoms of exposure are headache, upset stomach, coordination problems and irritated eyes, skin, nose and throat. Breathing very high levels can cause unconsciousness and even death.

What neutralizes xylene? ›

There is no antidote for xylene. Hemodialysis and hemoperfusion are ineffective.

What happens if you smell xylene? ›

The main effect of inhaling xylene vapor is depression of the central nervous system, with symptoms such as headache, dizziness, nausea and vomiting. The effects listed below can begin to occur with exposure to air levels of about 100 ppm.

What chemical category is xylene? ›

In organic chemistry, xylene or xylol (from Greek ξύλον (xylon) 'wood'; IUPAC name: dimethylbenzene) are any of three organic compounds with the formula (CH 3) 2C 6H 4.

What is the RCRA waste code for xylene? ›

F003 The following spent non-halogenated solvents: Xylene, acetone, ethyl acetate, ethyl benzene, ethyl ether, methyl isobutyl ketone, n-butyl alcohol, cyclohexanone, and methanol; all spent solvent mixtures/ blends containing, before use, only the above spent nonhalogenated solvents; and all spent solvent mixtures/ ...

Is xylene environmentally friendly? ›

Xylene has high acute (short-term) toxicity to aquatic life. It causes injury to various agricultural and ornamental crops. It also has high chronic (long-term) toxicity to aquatic life. There is not sufficient data to predict the acute or chronic toxicity of xylene on birds or land animals.

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